Thermally-conductive electromagnetic interference (EMI) absorbers with silicon carbide

ABSTRACT

According to various aspects, exemplary embodiments are disclosed of thermally-conductive EMI absorbers that generally includes thermally-conductive particles, EMI absorbing particles, and silicon carbide. The silicon carbide is present in an amount sufficient to synergistically enhance thermal conductivity and/or EMI absorption. By way of example, an exemplary embodiment of a thermally-conductive EMI absorber may include silicon carbide, magnetic flakes, manganese zinc ferrite, alumina, and carbonyl iron.

CROSS-REFERENCE TO RELATED APPLICATIONS

This patent application is also a continuation of U.S. patentapplication Ser. No. 14/928,189 filed Oct. 30, 2015 (published asUS2016/0234981 on Aug. 11, 2016 and issuing as U.S. Pat. No. 11,229,147on Jan. 18, 2022).

U.S. patent application Ser. No. 14/928,189 claims the benefit of andpriority to U.S. Provisional Patent Application No. 62/112,758 filedFeb. 6, 2015.

U.S. patent application Ser. No. 14/928,189 is a continuation-in-part ofU.S. patent application Ser. No. 14/683,870 filed Apr. 10, 2015(published as US2016/0233173 on Aug. 11, 2016).

U.S. patent application Ser. No. 14/928,189 also claimed the benefit ofand priority to U.S. Provisional Patent Application No. 62/112,758 filedFeb. 6, 2015.

The entire disclosures of the above applications are incorporated hereinby reference.

FIELD

The present disclosure generally relates to thermally-conductiveelectromagnetic interference (EMI) absorbers.

BACKGROUND

This section provides background information related to the presentdisclosure which is not necessarily prior art.

Electrical components, such as semiconductors, transistors, etc.,typically have pre-designed temperatures at which the electricalcomponents optimally operate. Ideally, the pre-designed temperaturesapproximate the temperature of the surrounding air. But the operation ofelectrical components generates heat which, if not removed, will causethe electrical component to operate at temperatures significantly higherthan its normal or desirable operating temperature. Such excessivetemperatures may adversely affect the operating characteristics of theelectrical component and the operation of the associated device.

To avoid or at least reduce the adverse operating characteristics fromthe heat generation, the heat should be removed, for example, byconducting the heat from the operating electrical component to a heatsink. The heat sink may then be cooled by conventional convection and/orradiation techniques. During conduction, heat may pass from theoperating electrical component to the heat sink either by direct surfacecontact between the electrical component and heat sink and/or by contactof the electrical component and heat sink surfaces through anintermediate medium or thermal interface material (TIM). The thermalinterface material may be used to fill the gap between thermal transfersurfaces, in order to increase thermal transfer efficiency as comparedto having the gap filled with air, which is a relatively poor thermalconductor.

In addition to generating heat, the operation of electronic devicesgenerates electromagnetic radiation within the electronic circuitry ofthe equipment. Such radiation may result in electromagnetic interference(EMI) or radio frequency interference (RFI), which can interfere withthe operation of other electronic devices within a certain proximity.Without adequate shielding, EMI/RFI interference may cause degradationor complete loss of important signals, thereby rendering the electronicequipment inefficient or inoperable.

A common solution to ameliorate the effects of EMI/RFI is through theuse of shields capable of absorbing and/or reflecting and/or redirectingEMI energy. These shields are typically employed to localize EMI/RFIwithin its source, and to insulate other devices proximal to the EMI/RFIsource.

The term “EMI” as used herein should be considered to generally includeand refer to EMI emissions and RFI emissions, and the term“electromagnetic” should be considered to generally include and refer toelectromagnetic and radio frequency from external sources and internalsources. Accordingly, the term shielding (as used herein) broadlyincludes and refers to mitigating (or limiting) EMI and/or RFI, such asby absorbing, reflecting, blocking, and/or redirecting the energy orsome combination thereof so that it no longer interferes, for example,for government compliance and/or for internal functionality of theelectronic component system.

SUMMARY

This section provides a general summary of the disclosure and is not acomprehensive disclosure of its full scope or all of its features.

According to various aspects, exemplary embodiments are disclosed ofthermally-conductive EMI absorbers that generally includesthermally-conductive particles, EMI absorbing particles, and siliconcarbide. The silicon carbide is present in an amount sufficient tosynergistically enhance thermal conductivity and/or EMI absorption. Byway of example, an exemplary embodiment of a thermally-conductive EMIabsorber may include silicon carbide, magnetic flakes, manganese zincferrite, alumina, and carbonyl iron.

Further areas of applicability will become apparent from the descriptionprovided herein. The description and specific examples in this summaryare intended for purposes of illustration only and are not intended tolimit the scope of the present disclosure.

DRAWINGS

The drawings described herein are for illustrative purposes only ofselected embodiments and not all possible implementations and are notintended to limit the scope of the present disclosure.

FIG. 1 is a line graph illustrating attenuation or absorption (indecibels per centimeter (dB/cm)) versus frequency (in Gigahertz (GHz))for two different thermally-conductive EMI absorbers including siliconcarbide, carbonyl iron powder, and alumina according to exemplaryembodiments, and also showing a thermally-conductive EMI absorber thatdoes not include any silicon carbide for comparison purposes;

FIG. 2 is a line graph illustrating attenuation (dB/cm) versus frequency(GHz) for two different thermally-conductive EMI absorbers includingsilicon carbide, carbonyl iron powder, and alumina according toexemplary embodiments;

FIG. 3 is a line graph illustrating transmission attenuation ratio (RTP)(in decibels (dB)) versus frequency (GHz) for two thermally-conductiveEMI absorbers including silicon carbide, carbonyl iron powder, alumina,manganese zinc (MnZn) ferrite, and magnetic flakes according toexemplary embodiments, where the thermally-conductive EMI absorbers hadthicknesses of 1 millimeter (mm) and 2.5 mm;

FIG. 4 is a line graph illustrating absorption power (%) versusfrequency (GHz) for two thermally-conductive EMI absorbers includingsilicon carbide, carbonyl iron powder, alumina, manganese zinc (MnZn)ferrite, and magnetic flakes according to exemplary embodiments, wherethe thermally-conductive EMI absorbers had thicknesses of 1 mm and 2.5mm;

FIG. 5 is a line graph illustrating attenuation (dB/cm) versus frequency(GHz) for a thermally-conductive EMI absorber including silicon carbide,carbonyl iron powder, alumina, manganese zinc (MnZn) ferrite, andmagnetic flakes according to exemplary embodiments according toexemplary embodiments;

FIG. 6 is a line graph illustrating magnetic permeability (u) versusfrequency (GHz) for a thermally-conductive EMI absorber includingsilicon carbide, carbonyl iron powder, alumina, manganese zinc (MnZn)ferrite, and magnetic flakes according to exemplary embodimentsaccording to exemplary embodiments; and

FIG. 7 is a line graph illustrating electrical permittivity (e) versusfrequency (GHz) for a thermally-conductive EMI absorber includingsilicon carbide, carbonyl iron powder, alumina, manganese zinc (MnZn)ferrite, and magnetic flakes according to exemplary embodimentsaccording to exemplary embodiments.

DETAILED DESCRIPTION

Example embodiments will now be described more fully with reference tothe accompanying drawings.

Disclosed herein are exemplary embodiments of thermally-conductive EMIabsorbers that include silicon carbide. For example, exemplaryembodiments are disclosed of thermally-conductive EMI absorbers thatinclude silicon carbide, carbonyl iron powder, and alumina. In someexemplary embodiments, a thermally-conductive EMI absorber may furtherinclude manganese zinc (MnZn) ferrite and magnetic flakes.

As disclosed herein, the inventors have discovered that silicon carbide(SiC) works synergistically with the thermally-conductive materials(e.g., Alumina (Al₂O₃), ceramics, etc.) and EMI absorbing materials(e.g., carbonyl iron powder (CIP), magnetic flakes, manganese zinc(MnZn) ferrite, other EMI absorbing materials, etc.) to enhance boththermal conductivity and EMI absorption (e.g., as shown in FIGS. 1, 2,and 5 , etc.). The resulting thermally-conductive EMI absorbers havehigh thermal conductivity (e.g., at least 2 Watts per meter per Kelvin(W/m-K) or higher, etc.) and high EMI absorption or attenuation (e.g.,at least 9 decibels per centimeter (dB/cm) at a frequency of at least 1GHz, at least 17 dB/cm at a frequency of at least 15 GHz, etc.). By wayof example only, exemplary embodiments are disclosed herein ofthermally-conductive EMI absorbers that may include silicon carbide(e.g., about 21 to 27 volume percent (vol %), etc.), carbonyl ironpowder (e.g., about 8 to 38 vol %, etc.), and alumina (e.g., about 6 to44 vol %, etc.). By way of further example only, exemplary embodimentsare also disclosed herein of thermally-conductive EMI absorbers that mayinclude silicon carbide (e.g., about 4 to 10 vol %, etc.), carbonyl ironpowder (e.g., about 3 to 5 vol %, etc.), alumina (e.g., about 18 to 23vol %, etc.), manganese zinc ferrite (e.g., about 27 to 40 vol %, etc.),and flaked magnetic material (e.g., about 2 to 4 vol %, etc.).

The art has not shown an instance where silicon carbide has actedsynergistically to provide improved thermal conductivity and high EMIabsorption. The following four examples show the synergistic effect thatthe silicon carbide has on the thermal conductivity and EMI absorption.From a practical point of view, a need in the art has been satisfied.Through the presence of the synergy that the silicon carbide has on thealumina and carbonyl iron powder in the first three exampleformulations, the inventors have created a thermally-conductive EMIabsorbing composition having better thermal conductivities with lessalumina and/or better absorption with less carbonyl iron powder than theconventional absorbers. In the fourth example formulation, the presenceof the manganese zinc ferrite and magnetic flakes along with the siliconcarbide, alumina, and carbonyl iron powder provides athermally-conductive EMI absorbing composition having exceptionally highattenuation at low frequencies, such as between 1 GHz and 5 GHz.

The following four example formulations are meant to illustrate thegeneral principles and properties of certain embodiments and are notintended to limit the scope of the claims. The volume percents of eachformulation may be varied in other exemplary embodiments to improve oroptimize certain properties of the produce.

In these example formulations, the silicon carbide had a mean particlesize of about 30 microns with particle sizes ranging from about 16microns to about 49 microns. The silicon carbide particles were mostlyspherical in shape. The range of particle sizes of one alumina particlewas from about 1 micron to about 9 microns (e.g., with a mean particlesize of about 2 microns, etc.). The range of particle sizes of the otheror second alumina particle was from about 26 microns to about 65 microns(e.g., with a mean particle size of about 45 microns, etc.). The rangeof particle sizes for the carbonyl iron particles was from about 1micron to about 6 microns. The silicon carbide, alumina, and carbonyliron particles were all mostly spherical in shape.

A first example formulation of a thermally-conductive EMI absorberincludes 37 volume percent of carbonyl iron powder, 26 volume percent ofsilicon carbide, 7 volume percent of alumina, 27.7 volume percent ofsilicone matrix, 2.2 volume percent of dispersant, and 0.1 volumepercent of cross-linker. In this first example, the dispersant wasIsopropyl triisostearoyl titanate, and the crosslinker wasMethylhydrogensiloxane-Dimethylsiloxane copolymer, hydride terminated.This first example formulation had a thermal conductivity of 3 W/m-K.

A second example formulation of a thermally-conductive EMI absorberincludes 9 volume percent of carbonyl iron powder, 22 volume percent ofsilicon carbide, 43 volume percent of alumina, 24.4 volume percent ofsilicone matrix, 1.5 volume percent of dispersant, and 0.1 volumepercent of cross-linker. In this second example, the dispersant wasIsopropyl triisostearoyl titanate, and the crosslinker wasMethylhydrogensiloxane-Dimethylsiloxane copolymer, hydride terminated.This second example formulation had a thermal conductivity of 4 W/m-K.

A third example formulation of a thermally-conductive EMI absorberincludes 10 volume percent of carbonyl iron powder, 27 volume percent ofsilicon carbide, 34 volume percent of alumina, 27.1 volume percent ofsilicone matrix, 1.8 volume percent of dispersant, and 0.1 volumepercent of cross-linker. In this third example, the dispersant wasIsopropyl triisostearoyl titanate, and the crosslinker wasMethylhydrogensiloxane-Dimethylsiloxane copolymer, hydride terminated.This third example formulation had a thermal conductivity of 3.5 W/m-K.

FIGS. 1 and 2 are exemplary line graphs illustrating attenuation orabsorption (dB/cm) versus frequency (GHz) for the first and secondformulations described above. For comparison purposes, FIG. 1 also showsattenuation or absorption (dB/cm) versus frequency (GHz) for aconventional thermally-conductive EMI absorber (labeled control in FIG.1 ) that does not include any silicon carbide. The results shown inFIGS. 1 and 2 are provided only for purposes of illustration and not forpurposes of limitation.

The conventional absorber (control) included 43 volume percent of byvolume of carbonyl iron powder, 0 volume percent of by volume of siliconcarbide, 22 volume percent of by volume alumina, 33.1 volume percent ofsilicone matrix, 1.7 volume percent of dispersant, and 0.2 volumepercent of cross-linker. For the control, the dispersant was Isopropyltriisostearoyl titanate, and the crosslinker wasMethylhydrogensiloxane-Dimethylsiloxane copolymer, hydride terminated.The control had a thermal conductivity of 2 W/m-K.

As compared to the three sample formulations, the conventional absorberhad the lowest thermal conductivity of 2 W/m-K. By comparison, the firstformulation had a higher thermal conductivity of 3 W/m-K despite havingless alumina of only 7% by volume. Thus, this shows the synergisticeffect that the silicon carbide had on the thermal conductivity.

A shown in FIG. 1 , the attenuation of the second formulation was betterthan the conventional absorber or control. This was despite the secondformulation having only 9% by volume of carbonyl iron powder, ascompared to the conventional absorber's 43% by volume of carbonyl ironpowder. The second formulation also had a thermal conductivity of 4W/m-K, which was double the thermal conductivity of the conventionalabsorber.

FIG. 1 also shows that the attenuation of the first formulation wasbetter or higher than (e.g., about a threefold increase (3×), etc.) theconventional absorber. The first formulation also had a thermalconductivity of 3 W/m-K, which is higher than the conventionalabsorber's thermal conductivity of 2 W/m-K.

A fourth example formulation of a thermally-conductive EMI absorberincludes 32.1 volume percent manganese zinc ferrite, 3 volume percent offlaked magnetic material (e.g., magnetic flakes or flaked alloycontaining iron, silicon, and aluminum, etc.), 4 volume percent ofcarbonyl iron powder, 4.8 volume percent of silicon carbide, 4.1 volumepercent of silicone oil, 1.6 volume percent of titanate coupling agent,2.9 volume percent of 5.5 wt % cross-linker in silicone oil, 19.5 volumepercent of alumina (e.g., 3.7 volume percent of a first type of grade ofalumina having a mean particle size of about 2 microns, and 15.8 volumepercent of a second type or grade of alumina having a mean particle sizeof about 45 microns, etc.), and 28 volume percent of silicone gel (or 14volume percent of part A silicone gel, and 14 volume percent of part Bsilicone gel).

In terms of weight percent, the fourth example formulation included 47.7weight percent of manganese zinc ferrite, 5.9 weight percent of flakedmagnetic material, 9 weight percent of carbonyl iron powder, 4.5 weightpercent of silicon carbide, 1.2 weight percent of silicone oil, 0.5weight percent of titanate coupling agent, 0.8 weight percent of 5.5 wt% cross-linker in silicone oil, 22.5 weight percent of alumina (e.g.,4.5 weight percent of a first type of grade of alumina having a meanparticle size of about 2 microns, and 18 weight percent of a second typeor grade of alumina having a mean particle size of about 45 microns,etc.), and 8 weight percent of silicone gel (or 4 weight percent of partA silicone gel, and 4 weight percent of part B silicone gel).

Also in this fourth example formulation, the manganese zinc ferrite hada mean particle size of about 6.5 microns and an irregular sphericalshape. The flaked magnetic material had a diameter of about 80 micronsand a thickness of about 1 micron, thereby having an aspect ratio ofabout 80. The flaked magnetic material may comprise alloy containingiron, silicon, and aluminum, such as an alloy including about 6 to 12%of silicon, about 3 to 10% of aluminum, and iron in the remainingpercentage (e.g., a magnetic metal alloy including about 85% iron, about9.5% silicon, and about 5.5% aluminum, a magnetic metal alloy includingabout 85% iron, about 9% silicon, and about 6% aluminum etc.).

This fourth example formulation had a thermal conductivity of 2 W/m-K ormore. This fourth example formulation also had an attenuation of atleast about 9 decibels per centimeter for frequencies from 1 gigahertzto 6 gigahertz.

FIGS. 3 through 7 are exemplary line graphs illustrating performancedata for thermally-conductive EMI absorbers having the fourthformulation described above. The results shown in FIGS. 3 through 8 areprovided only for purposes of illustration and not for purposes oflimitation.

More specifically, FIG. 3 is a line graph illustrating transmissionattenuation ratio (RTP) (dB) versus frequency (GHz). Generally, FIG. 3shows that the thermally-conductive EMI absorber having the fourthformulation had good RTP (e.g., greater than about 2 dB, etc.) forfrequencies between 1 GHz and 6 GHz. By way of background, transmissionattenuation ratio is a 50 ohm microstrip measurement based on IEC6233where:Rtp=−10 Log(10^(|S21|/10)|(1−10^(|S11|/10)))1=>energy that you put in the lineS21=>energy passes thru the lineS11=>energy that is reflected

FIG. 4 is a line graph illustrating absorption power (%) versusfrequency (GHz). Generally, FIG. 4 shows that the thermally-conductiveEMI absorber having the fourth formulation had good absorption power (%)(e.g., greater than 30%, etc.) for frequencies between 1 GHz and 6 GHz.For example, the 2.5 millimeter thick sample had an absorption power ofat least about 50% at 1 GHz and greater than about 70% for frequenciesbetween 2 GHz and 6 GHz. Also, for example, the 1 millimeter thicksample had an absorption power of at least about 30% at 1 GHz andgreater than about 70% for frequencies between 2 GHz and 6 GHz.

FIG. 5 is a line graph illustrating attenuation (dB/cm) versus frequency(GHz). Generally, FIG. 5 shows that the thermally-conductive EMIabsorber having the fourth formulation had good attenuation (e.g.,greater than 9 dB/cm from 1 GHz to 6 GHz, etc.) for frequencies between1 GHz and 18 GHz. For example, the thermally-conductive EMI absorberhaving the fourth formulation had an attenuation of at least about 11dB/cm at 1 GHz, at least about 25 dB/cm at 2 GHz, at least about 36dB/cm at 3 GHz, at least about 44 dB/cm at 4 GHz, at least about 49dB/cm at 5 GHz, and at least about 52 dB/cm at 6 GHz.

FIGS. 6 and 7 are line graphs respectively illustrating magneticpermeability (u) and electrical permittivity (e) versus frequency (GHz)for the thermally-conductive EMI absorber having the fourth formulation.Generally, permeability and permittivity are measured and may then beentered into an equation to calculate attenuation, which reflects EMIabsorption. A material with higher imaginary magnetic permeability (u″)and higher imaginary electrical permittivity (e″) will have a higherattenuation. Other properties of the material may also be derived fromthese four parameters, i.e., real magnetic permeability (u′) andimaginary magnetic permeability (u″) shown in FIG. 6 , and the realelectrical permittivity (e′) and imaginary electrical permittivity (e″)shown in FIG. 7 .

FIGS. 6 and 7 show that the thermally-conductive EMI absorber having thefourth formulation had good magnetic permeability and electricalpermittivity for frequencies between 1 GHz and 6 GHz.

Accordingly, exemplary embodiments are disclosed of thermally-conductiveEMI absorbers having high EMI absorption or attenuation (e.g., at least9 decibels per centimeter (dB/cm) at a frequency of at least 1 GHz,etc.) at low frequencies (e.g., from 1 GHz to 6 GHz, etc.) and highthermal conductivity (e.g., at least 2 W/mk or higher, etc.). Thethermally-conductive EMI absorber may also have a high magneticpermeability (e.g., a magnetic permeability of 23 at 10 MHz, etc.). Asdisclosed herein, exemplary embodiments of thermally-conductive EMIabsorbers may include a material (e.g., soft silicone gel, etc.)including silicon carbide, alumina, carbonyl iron powder, manganese zinc(MnZn) ferrite, and magnetic flakes or flaked magnetic materials (e.g.,flaked Sendust magnetic metal powder, flaked permalloy, a flaked alloycontaining iron, silicon, and aluminum, a flaked alloy containing ironand nickel, a flaked material having a relatively high permeability,etc.) for good heat transfer and microwave absorption.

By way of example, the magnetic flakes or flaked magnetic materials maycomprise an alloy containing iron, silicon, and aluminum, such as analloy including about 6 to 12% of silicon, about 3 to 10% of aluminum,and iron in the remaining percentage (e.g., a magnetic metal alloyincluding about 85% iron, about 9.5% silicon, and about 5.5% aluminum, amagnetic metal alloy including about 85% iron, about 9% silicon, andabout 6% aluminum etc.), etc. By way of further example, the magneticflakes or flaked magnetic materials may comprise an alloy containingiron and aluminum, such as a nickel-iron magnetic alloy including about20% iron and about 80% nickel, etc. Also, by way of example, thethermally-conductive EMI absorber may be placed between a chip (or otherheat source) and a heat sink (or other heat dissipating device orcomponent) to conduct heat away and prevents (or at least inhibit) EMIenergy from reaching the heat sink and radiating out. In which case, thethermally-conductive EMI absorber may allow for the elimination of anoise suppressor.

For EMI absorption or attenuation, each of first, second, and thirdsample formulations included carbonyl iron powder in the amounts of 37vol %, 9 vol %, and 10 vol %, respectively. Advantageously, carbonyliron powder offers better performance for frequencies of interestranging from about 5 GHz to about 15 GHz. Other exemplary embodimentsmay include one or more other EMI absorbers instead of or in addition tocarbonyl iron powder and/or in different amounts. For example, thefourth formulation also included manganese zinc ferrite and magneticflakes or flaked alloy containing iron, silicon, and aluminum inaddition to carbonyl iron powder. More specifically, the example fourthformulation included 32.1 volume percent manganese zinc ferrite, 3volume percent of flaked magnetic material, and 4 volume percent ofcarbonyl iron powder. Other exemplary embodiments may include one ormore other EMI absorbers instead of or in addition to manganese zincferrite, magnetic flakes, and/or carbonyl iron powder and/or indifferent amounts.

Examples of EMI absorbers that may be used in exemplary embodimentsinclude iron silicide, iron particles, iron oxides, iron alloys,iron-chrome compounds, SENDUST, permalloy, ferrites, magnetic alloys,magnetic powders, magnetic flakes, magnetic particles, nickel-basedalloys and powders, chrome alloys, carbonyl iron (e.g., carbonyl ironpowder, etc.), combinations thereof, etc. The EMI absorbers may compriseone or more of granules, spheroids, microspheres, ellipsoids, irregularspheroids, strands, flakes, particles, powder, and/or a combination ofany or all of these shapes. In some exemplary embodiments, the EMIabsorber may comprise magnetic material, such as a magnetic materialwith a magnetic relative permeability greater than 2 at 1.0 Megahertz.For example, the EMI absorber may have a relative magnetic permeabilitygreater than about 3.0 at approximately 1.0 Gigahertz, and greater thanabout 1.5 at 10 Gigahertz. Alternative embodiments may include EMIabsorbers configured differently and in different sizes. These specificnumerical values provided in this paragraph (as are all numerical valuesdisclosed herein) are for purposes of illustration only and not forpurposes of limitation.

For thermal conductivity, each of the first, second, third, and fourthexample formulations included alumina in the amounts of 7 vol %, 43 vol%, 34 vol %, and 19.5 vol %, respectively. Advantageously, alumina isrelatively low cost and is available in various particle sizes, whichallows for nesting or packing of alumina particles to increase volumeloading of the alumina for higher thermal conductivity. Other exemplaryembodiments may include one or more other thermal conductors orthermally-conductive fillers instead of or in addition to alumina. Forexample, some exemplary embodiments may include otherthermally-conductive fillers having a thermal conductivity of at least 1W/m-K (Watts per meter-Kelvin) or more, such as a copper filler havingthermal conductivity up to several hundred W/m-K, etc. Also, forexample, other exemplary embodiments may include one or more of thefollowing thermally-conductive fillers: zinc oxide, boron nitride,silicon nitride, aluminum, aluminum nitride, alumina, iron, metallicoxides, graphite, ceramics, combinations thereof (e.g., alumina and zincoxide, etc.), etc. In addition, exemplary embodiments may also includedifferent grades (e.g., different sizes, different purities, differentshapes, etc.) of the same (or different) thermally-conductive fillers.For example, a thermally-conductive EMI absorber may include twodifferent sizes of boron nitride. By varying the types and grades ofthermally-conductive fillers, the final characteristics of thethermally-conductive EMI absorber (e.g., thermal conductivity, cost,hardness, etc.) may be varied as desired. In exemplary embodimentsdisclosed herein, the thermally-conductive EMI absorbers may have athermal conductivity of at least 2 W/m-K or higher.

The first, second, third, and fourth example formulations included asilicone matrix (e.g., silicone elastomer, silicone gel, etc.). In otherexemplary embodiments, the matrix may comprise other materials, such asother thermoset polymers including polyurethanes, rubber (e.g., SBR,nitrile, butyl, isoprene, EPDM, etc.), etc. By way of additionalexamples, the matrix material may comprise thermoplastic matrixmaterials, polyolefins, polyamides, polyesters, polyurethanes,polycarbonates, polystyrene and styrenic copolymers, acrylnitriles,polyvinyl chlorides, polysulfones, acetals, polyarlyates,polypropylenes, surlyns, polyethylene terephthalates, polystyrenes,combinations thereof, etc. The matrix may be selected based on theparticular fillers (e.g., silicon carbide, alumina, carbonyl ironpowder, manganese zinc ferrite, magnetic flakes, other fillers, etc.)and/or particular amounts of fillers that may be suspended or added tothe matrix. The matrix may also be substantially transparent toelectromagnetic energy so that the matrix does not impede the absorptiveaction of the EMI absorbing filler in the matrix. For example, a matrixexhibiting a relative dielectric constant of less than approximately 4and a loss tangent of less than approximately 0.1 is sufficientlytransparent to EMI. Values outside this range, however, are alsocontemplated as these specific numerical values provided in thisparagraph (as are all numerical values disclosed herein) are forpurposes of illustration only and not for purposes of limitation.

By way of example only, the following is a description of an exemplaryprocess that may be used for making a thermally-conductive EMI absorberthat includes silicon carbide, carbonyl iron powder, and alumina, suchas a thermally-conductive EMI absorber having the first, second, orthird example formulation described above. In a first step or operation,a high speed mixer may be used to mix silicone gel parts A and B, alongwith the dispersant and cross linker until well blended (e.g., mixingfor about 2 minutes, etc.). In a second step or operation, carbonyl ironpowder may then be slowly added while mixing (e.g., for about 5 minutes,etc.) until the carbonyl iron powder is well mixed and wetted withsilicone polymer. In a third step or operation, silicon carbide may nextbe slowly added while mixing (e.g., for about 5 minutes, etc.) untilwell blended. In a fourth step or operation, alumina or aluminum oxidehaving a first or smaller particle size may be slowly added while mixing(e.g., for about 5 minutes, etc.) until well blended. In a fifth step oroperation, alumina or aluminum oxide having a second or larger particlesize may be slowly added while mixing (e.g., for about 5 minutes, etc.)until well blended. In a sixth step or operation, the mixing may becontinued (e.g., for about 5 minutes, etc.) until the mixture isthoroughly smooth. In a seventh step or operation, the mixture may beplaced under vacuum (e.g., for about 5 minutes, etc.) to remove air. Aneighth step or operation may include setting a gap between calenderingrolls for desired product thickness. In a ninth step or operation, themixture may be rolled between two release liners in-between thecalendering rolls. In a tenth step of operation, the resulting sheetsmay be cured in an oven, e.g., at 285 degrees Fahrenheit for about 1 to2 hours depending on thickness, etc.

By way of further example only, the following is a description of anexemplary process that may be used for making a thermally-conductive EMIabsorber that includes silicon carbide, carbonyl iron powder, alumina,manganese zinc ferrite, and magnetic flakes, such as athermally-conductive EMI absorber having the fourth formulationdescribed above. In a first step or operation, a mixer may be used tomix silicone gel parts A and B, along with a dispersant and cross linkeruntil well blended (e.g., mixing for about 2 minutes, etc.). In a secondstep or operation, carbonyl iron powder may then be slowly added whilemixing (e.g., for about 5 minutes, etc.) until the carbonyl iron powderis well mixed and wetted with silicone polymer. In a third step oroperation, silicon carbide may next be slowly added while mixing (e.g.,for about 5 minutes, etc.) until well blended. In a fourth step oroperation, alumina or aluminum oxide having a first or smaller particlesize may be slowly added while mixing (e.g., for about 5 minutes, etc.)until well blended. In a fifth step or operation, alumina or aluminumoxide having a second or larger particle size may be slowly added whilemixing (e.g., for about 5 minutes, etc.) until well blended. In a sixthstep or operation, manganese zinc ferrite may next be slowly added whilemixing (e.g., for about 5 minutes, etc.) until well blended. In aseventh step or operation, magnetic flakes may be slowly added whilemixing (e.g., for about 30 minutes, etc.) until the magnetic flakes arewell mixed and wetted with silicone polymer. In an eighth step oroperation, the mixing may be continued (e.g., for about 10 minutes,etc.) until the mixture is thoroughly smooth. In a ninth step ofoperation, the resulting sheets may be cured in an oven (e.g., at 285degrees Fahrenheit, etc.) for a predetermined amount of time dependingon thickness (e.g., for about 6 hours or more for thicknesses of 0.1inch to have a clean peel, etc.). Some additional steps that may occurbefore the curing process may include placing the mixture under vacuum(e.g., for about 5 minutes, etc.) to remove air, setting a gap betweencalendering rolls for desired product thickness, and rolling the mixturebetween two release liners in-between the calendering rolls.

In some exemplary embodiments, a thermally-conductive EMI absorber mayfurther include an adhesive layer, such as a pressure-sensitive adhesive(PSA), etc. The pressure-sensitive adhesive (PSA) may be generally basedon compounds including acrylic, silicone, rubber, and combinationsthereof. The adhesive layer can be used to affix thethermally-conductive EMI absorbers to a portion of an EMI shield, suchas to a single piece EMI shield, to a cover, lid, frame, or otherportion of a multi-piece shield, to a discrete EMI shielding wall, etc.Alternative affixing methods can also be used such as, for example,mechanical fasteners. In other exemplary embodiments, thethermally-conductive EMI absorber may be tacky or self-adherent suchthat the thermally-conductive EMI absorber may be self-adhered toanother surface without any adhesive layer.

In some embodiments, a thermally-conductive EMI absorber may be attachedto a lid or cover of an EMI shield (e.g., a lid or cover of asingle-piece EMI shield, a removable lid or cover of a multi-piece EMIshield, a lid or cover of an EMI shield from Laird Technologies, etc.).The thermally-conductive EMI absorber may be placed, for example, on aninner surface of the cover or lid. Alternatively, thethermally-conductive EMI absorber may be placed, for example, on anouter surface of the cover or lid. The thermally-conductive EMI absorbermay be placed on an entire surface of the cover or lid or on less thanan entire surface. For example, the thermally-conductive EMI absorbermay be placed on a frame or base and a separate thermally-conductive EMIabsorber may be placed on a removable lid or cover that is attachable tothe frame or base. The thermally-conductive EMI absorber may be appliedat virtually any location at which it would be desirable to have athermally-conductive EMI absorber.

In exemplary embodiments, a thermally-conductive EMI absorber may beused to define or provide part of a thermally-conductive heat path froma heat source to a heat dissipating device or component. Athermally-conductive EMI absorber disclosed herein may be used, forexample, to help conduct thermal energy (e.g., heat, etc.) away from aheat source of an electronic device (e.g., one or more heat generatingcomponents, central processing unit (CPU), die, semiconductor device,etc.). For example, a thermally-conductive EMI absorber may bepositioned generally between a heat source and a heat dissipating deviceor component (e.g., a heat spreader, a heat sink, a heat pipe, a deviceexterior case or housing, etc.) to establish a thermal joint, interface,pathway, or thermally-conductive heat path along which heat may betransferred (e.g., conducted) from the heat source to the heatdissipating device. During operation, the thermally-conductive EMIabsorber may then function to allow transfer (e.g., to conduct heat,etc.) of heat from the heat source along the thermally-conductive pathto the heat dissipating device. The thermally-conductive EMI absorbermay be used similarly to a thermal gap pad and allow for the eliminationof a noise suppressor.

Example embodiments of thermally-conductive EMI absorbers disclosedherein may be used with a wide range of heat dissipation devices orcomponents (e.g., a heat spreader, a heat sink, a heat pipe, a deviceexterior case or housing, etc.), heat-generating components, heatsources, heat sinks, and associated devices. For example, a heat sourcemay comprise one or more heat generating components or devices (e.g., aCPU, die within underfill, semiconductor device, flip chip device,graphics processing unit (GPU), digital signal processor (DSP),multiprocessor system, integrated circuit, multi-core processor, etc.).Generally, a heat source may comprise any component or device that has ahigher temperature than the thermally-conductive EMI absorber orotherwise provides or transfers heat to the thermally-conductive EMIabsorber regardless of whether the heat is generated by the heat sourceor merely transferred through or via the heat source. By way of exampleonly, exemplary applications include printed circuit boards, highfrequency microprocessors, central processing units, graphics processingunits, laptop computers, notebook computers, desktop personal computers,computer servers, thermal test stands, etc. Accordingly, aspects of thepresent disclosure should not be limited to use with any one specifictype of heat-generating component, heat source, or associated device.

In some exemplary embodiments, the thermally-conductive EMI absorber maybe configured to have sufficient conformability, compliability, and/orsoftness to allow the thermally-conductive EMI absorber to closelyconform to a mating surface when placed in contact with the matingsurface, including a non-flat, curved, or uneven mating surface. In someexemplary embodiments, the thermally-conductive EMI absorber hassufficient deformability, compliance, conformability, compressibility,and/or flexibility for allowing the thermally-conductive EMI absorber torelatively closely conform to the size and outer shape of an electroniccomponent when placed in contact with the electronic component.

In some exemplary embodiments, the thermally-conductive EMI absorber isconformable even without undergoing a phase change or reflow. In otherexemplary embodiments, the thermally-conductive EMI absorber maycomprise a phase change material. In some exemplary embodiments, thethermally-conductive EMI absorber may comprise a non-phase change gapfiller, gap pad, or putty that is conformable without having to melt orundergo a phase change.

The thermally-conductive EMI absorber may be able to adjust fortolerance or gaps by deflecting at low temperatures (e.g., roomtemperature of 20° C. to 25° C., etc.). By way of example, athermally-conductive EMI absorbers may have a Young's modulus of lessthan or equal to about 300 pound force per square inch (lpf/in²) or 2.1megapascals (MPa). In exemplary embodiments, a thermally-conductive EMIabsorber may have a Young's modulus that falls within a range from about200 lbf/in² to about 300/in² or from about 1.4 MPa to about 2.1 MPa.Also, by way of example, a thermally-conductive EMI absorbers may have aShore 00 Hardness less than or equal to 60. In exemplary embodiments, athermally-conductive EMI absorber may have a Shore 00 Hardness valuethat falls within a range from about 50 to about 60.

In some exemplary embodiments, the thermally-conductive EMI absorber maybe conformable and have sufficient compressibility and flexibility forallowing the thermally-conductive EMI absorber to relatively closelyconform to the size and outer shape of an electrical component whenplaced in contact with the electrical component. For example, athermally-conductive EMI absorber may be along the inner surface of acover of an EMI shield such that the thermally-conductive EMI absorberis compressed against the electrical component when the EMI shield isinstalled to a printed circuit board over the electrical component. Byengaging the electrical component in this relatively close fitting andencapsulating manner, the thermally-conductive EMI absorber can conductheat away from the electrical component to the cover in dissipatingthermal energy.

In some embodiments, a thermally-conductive EMI absorber may be formedas a tape. The tape, for example, can be stored on a roll. In someembodiments, desired application shapes (e.g., rectangle, circle,ellipse, etc.) can be die-cut from the thermally-conductive EMIabsorber, thereby yielding thermally-conductive EMI absorbers of anydesired two-dimensional shape. Accordingly, the thermally-conductive EMIabsorber can be die-cut to produce the desired outlines of anapplication shape.

In operation, a thermally-conductive EMI absorber according to exemplaryembodiments disclosed herein may be operable for absorbing a portion ofthe EMI incident upon the EMI absorber, thereby reducing transmission ofEMI therethrough over a range of operational frequencies (e.g., afrequency range from about 1 GHz to at least about 5 GHz, a frequencyrange from about 5 GHz to at least about 15 GHz, a frequency range fromabout 2 GHz to at least about 18 GHz, etc.). The EMI absorber may removea portion of the EMI from the environment through power dissipationresulting from loss mechanisms. These loss mechanisms includepolarization losses in a dielectric material and conductive, or ohmic,losses in a conductive material having a finite conductivity.

By way of background, EMI absorbers function to absorb electromagneticenergy (that is, EMI). EMI absorbers convert electromagnetic energy intoanother form of energy through a process commonly referred to as a loss.Electrical loss mechanisms include conductivity losses, dielectriclosses, and magnetization losses. Conductivity losses refer to areduction in EMI resulting from the conversion of electromagnetic energyinto thermal energy. The electromagnetic energy induces currents thatflow within an EMI absorber having a finite conductivity. The finiteconductivity results in a portion of the induced current generating heatthrough a resistance. Dielectric losses refer to a reduction in EMIresulting from the conversion of electromagnetic energy into mechanicaldisplacement of molecules within an absorber having a non-unitaryrelative dielectric constant. Magnetic losses refer to a reduction inEMI resulting from the conversion of electromagnetic energy into arealignment of magnetic moments within an EMI absorber.

Example embodiments are provided so that this disclosure will bethorough and will fully convey the scope to those who are skilled in theart. Numerous specific details are set forth such as examples ofspecific components, devices, and methods, to provide a thoroughunderstanding of embodiments of the present disclosure. It will beapparent to those skilled in the art that specific details need not beemployed, that example embodiments may be embodied in many differentforms, and that neither should be construed to limit the scope of thedisclosure. In some example embodiments, well-known processes,well-known device structures, and well-known technologies are notdescribed in detail. In addition, advantages and improvements that maybe achieved with one or more exemplary embodiments of the presentdisclosure are provided for purpose of illustration only and do notlimit the scope of the present disclosure, as exemplary embodimentsdisclosed herein may provide all or none of the above mentionedadvantages and improvements and still fall within the scope of thepresent disclosure.

Specific dimensions, specific materials, and/or specific shapesdisclosed herein are example in nature and do not limit the scope of thepresent disclosure. The disclosure herein of particular values andparticular ranges of values for given parameters are not exclusive ofother values and ranges of values that may be useful in one or more ofthe examples disclosed herein. Moreover, it is envisioned that any twoparticular values for a specific parameter stated herein may define theendpoints of a range of values that may be suitable for the givenparameter (i.e., the disclosure of a first value and a second value fora given parameter can be interpreted as disclosing that any valuebetween the first and second values could also be employed for the givenparameter). For example, if Parameter X is exemplified herein to havevalue A and also exemplified to have value Z, it is envisioned thatparameter X may have a range of values from about A to about Z.Similarly, it is envisioned that disclosure of two or more ranges ofvalues for a parameter (whether such ranges are nested, overlapping ordistinct) subsume all possible combination of ranges for the value thatmight be claimed using endpoints of the disclosed ranges. For example,if parameter X is exemplified herein to have values in the range of1-10, or 2-9, or 3-8, it is also envisioned that Parameter X may haveother ranges of values including 1-9, 1-8, 1-3, 1-2, 2-10, 2-8, 2-3,3-10, and 3-9.

The terminology used herein is for the purpose of describing particularexample embodiments only and is not intended to be limiting. As usedherein, the singular forms “a”, “an” and “the” may be intended toinclude the plural forms as well, unless the context clearly indicatesotherwise. The terms “comprises,” “comprising,” “including,” and“having,” are inclusive and therefore specify the presence of statedfeatures, integers, steps, operations, elements, and/or components, butdo not preclude the presence or addition of one or more other features,integers, steps, operations, elements, components, and/or groupsthereof. The method steps, processes, and operations described hereinare not to be construed as necessarily requiring their performance inthe particular order discussed or illustrated, unless specificallyidentified as an order of performance. It is also to be understood thatadditional or alternative steps may be employed.

When an element or layer is referred to as being “on”, “engaged to”,“connected to” or “coupled to” another element or layer, it may bedirectly on, engaged, connected or coupled to the other element orlayer, or intervening elements or layers may be present. In contrast,when an element is referred to as being “directly on,” “directly engagedto”, “directly connected to” or “directly coupled to” another element orlayer, there may be no intervening elements or layers present. Otherwords used to describe the relationship between elements should beinterpreted in a like fashion (e.g., “between” versus “directlybetween,” “adjacent” versus “directly adjacent,” etc.). As used herein,the term “and/or” includes any and all combinations of one or more ofthe associated listed items.

The term “about” when applied to values indicates that the calculationor the measurement allows some slight imprecision in the value (withsome approach to exactness in the value; approximately or reasonablyclose to the value; nearly). If, for some reason, the imprecisionprovided by “about” is not otherwise understood in the art with thisordinary meaning, then “about” as used herein indicates at leastvariations that may arise from ordinary methods of measuring or usingsuch parameters. For example, the terms “generally”, “about”, and“substantially” may be used herein to mean within manufacturingtolerances. Or for example, the term “about” as used herein whenmodifying a quantity of an ingredient or reactant of the invention oremployed refers to variation in the numerical quantity that can happenthrough typical measuring and handling procedures used, for example,when making concentrates or solutions in the real world throughinadvertent error in these procedures; through differences in themanufacture, source, or purity of the ingredients employed to make thecompositions or carry out the methods; and the like. The term “about”also encompasses amounts that differ due to different equilibriumconditions for a composition resulting from a particular initialmixture. Whether or not modified by the term “about”, the claims includeequivalents to the quantities.

Although the terms first, second, third, etc. may be used herein todescribe various elements, components, regions, layers and/or sections,these elements, components, regions, layers and/or sections should notbe limited by these terms. These terms may be only used to distinguishone element, component, region, layer or section from another region,layer or section. Terms such as “first,” “second,” and other numericalterms when used herein do not imply a sequence or order unless clearlyindicated by the context. Thus, a first element, component, region,layer or section could be termed a second element, component, region,layer or section without departing from the teachings of the exampleembodiments.

Spatially relative terms, such as “inner,” “outer,” “beneath”, “below”,“lower”, “above”, “upper” and the like, may be used herein for ease ofdescription to describe one element or feature's relationship to anotherelement(s) or feature(s) as illustrated in the figures. Spatiallyrelative terms may be intended to encompass different orientations ofthe device in use or operation in addition to the orientation depictedin the figures. For example, if the device in the figures is turnedover, elements described as “below” or “beneath” other elements orfeatures would then be oriented “above” the other elements or features.Thus, the example term “below” can encompass both an orientation ofabove and below. The device may be otherwise oriented (rotated 90degrees or at other orientations) and the spatially relative descriptorsused herein interpreted accordingly.

The foregoing description of the embodiments has been provided forpurposes of illustration and description. It is not intended to beexhaustive or to limit the disclosure. Individual elements, intended orstated uses, or features of a particular embodiment are generally notlimited to that particular embodiment, but, where applicable, areinterchangeable and can be used in a selected embodiment, even if notspecifically shown or described. The same may also be varied in manyways. Such variations are not to be regarded as a departure from thedisclosure, and all such modifications are intended to be includedwithin the scope of the disclosure.

What is claimed is:
 1. A thermally-conductive electromagneticinterference (EMI) absorber comprising a matrix loaded withthermally-conductive particles, EMI absorbing particles, and siliconcarbide, wherein the silicon carbide is present in a predeterminedamount sufficient to synergistically enhance both thermal conductivityand EMI absorption, wherein the EMI absorbing particles comprisecarbonyl iron, and the thermally-conductive particles comprise alumina;wherein: the thermally-conductive EMI absorber includes at least about 6volume percent of the alumina, at least about 8 volume percent of thecarbonyl iron, and at least about 21 volume percent of the siliconcarbide; or the thermally-conductive EMI absorber includes about 2 to 4volume percent of magnetic flakes, about 3 to 5 volume percent of thecarbonyl iron, about 18 to 23 volume percent of the alumina, about 27 to40 volume percent of manganese zinc ferrite, and about 4 to 10 volumepercent of the silicon carbide.
 2. The thermally-conductive EMI absorberof claim 1, wherein the thermally-conductive EMI absorber includes about6 to 44 volume percent of the alumina, about 8 to 38 volume percent ofthe carbonyl iron, and about 21 to 27 volume percent of the siliconcarbide.
 3. The thermally-conductive EMI absorber of claim 1, whereinthe matrix comprises a silicone elastomer matrix.
 4. Thethermally-conductive EMI absorber of claim 1, wherein the matrixcomprises a silicone elastomer matrix loaded with the magnetic flakes,the carbonyl iron, the alumina, the manganese zinc ferrite, and thesilicon carbide such that the thermally-conductive EMI absorber includes2 to 4 volume percent of the magnetic flakes, 3 to 5 volume percent ofthe carbonyl iron, 18 to 23 volume percent of the alumina, 27 to 40volume percent of the manganese zinc ferrite, and 4 to 10 volume percentof the silicon carbide.
 5. The thermally-conductive EMI absorber ofclaim 1, wherein the matrix comprises a silicone elastomer matrix loadedwith the carbonyl iron, the alumina, and the silicon carbide such thatthe thermally-conductive EMI absorber includes 6 to 44 volume percent ofthe alumina, 8 to 38 volume percent of the carbonyl iron, and 21 to 27volume percent of the silicon carbide.
 6. The thermally-conductive EMIabsorber of claim 1, wherein the matrix comprises a silicone elastomermatrix loaded with the carbonyl iron, the alumina, and the siliconcarbide such that the thermally-conductive EMI absorber includes atleast 6 volume percent of the alumina, at least 8 volume percent of thecarbonyl iron, and at least 21 volume percent of the silicon carbide. 7.The thermally-conductive EMI absorber of claim 1, wherein: thethermally-conductive EMI absorber includes 43 volume percent of thealumina, 9 volume percent of the carbonyl iron, and 22 volume percent ofthe silicon carbide; and the 22 volume percent of the silicon carbide isthe predetermined amount sufficient to synergistically enhance boththermal conductivity and EMI absorption such that thethermally-conductive EMI absorber has better thermal conductivity andbetter absorption than a control absorber including 0 volume percent ofsilicon carbide, 22 volume percent of alumina, and 43 volume percent ofcarbonyl iron.
 8. The thermally-conductive EMI absorber of claim 1,wherein: the thermally-conductive EMI absorber includes about 7 volumepercent of the alumina, about 37 volume percent of the carbonyl iron,about 26 volume percent of the silicon carbide, the thermally-conductiveEMI absorber has a thermal conductivity of about 3 Watts per meter perKelvin, and the thermally-conductive EMI absorber has an attenuation ofat least about 9 decibels per centimeter at a frequency of at least 5gigahertz and/or at least about 17 decibels per centimeter at afrequency of at least 15 gigahertz; or the thermally-conductive EMIabsorber includes about 43 volume percent of the alumina, about 9 volumepercent of the carbonyl iron, about 22 volume percent of the siliconcarbide, the thermally-conductive EMI absorber has a thermalconductivity of about 4 Watts per meter per Kelvin, thethermally-conductive EMI absorber has an attenuation of at least about 9decibels per centimeter at a frequency of at least 5 gigahertz and/or atleast about 17 decibels per centimeter at a frequency of at least 15gigahertz; or the thermally-conductive EMI absorber includes about 34volume percent of the alumina, about 10 volume percent of the carbonyliron, about 27 volume percent of the silicon carbide, thethermally-conductive EMI absorber has a thermal conductivity of about3.5 Watts per meter per Kelvin, and the thermally-conductive EMIabsorber has an attenuation of at least about 9 decibels per centimeterat a frequency of at least 5 gigahertz and/or at least about 17 decibelsper centimeter at a frequency of at least 15 gigahertz.
 9. Thethermally-conductive EMI absorber of claim 1, wherein thethermally-conductive EMI absorber further comprises an adhesive layerfor affixing the thermally-conductive EMI absorber to an inner surfaceof an EMI shield such that the thermally-conductive EMI absorber iscompressible against a component on a printed circuit board when the EMIshield is installed to the printed circuit board over the component. 10.The thermally-conductive EMI absorber of claim 1, wherein thethermally-conductive EMI absorber includes about 3 volume percent of themagnetic flakes, about 4 volume percent of the carbonyl iron, about 19.5volume percent of the alumina, about 32.1 volume percent of themanganese zinc ferrite, and about 4.8 volume percent of the siliconcarbide.
 11. The thermally-conductive EMI absorber of claim 1, whereinthe thermally-conductive EMI absorber is configured to have a thermalconductivity of at least 2 Watts per meter per Kelvin, and anattenuation of at least about 9 decibels per centimeter for frequenciesfrom 1 gigahertz to 6 gigahertz.
 12. The thermally-conductive EMIabsorber of claim 1, wherein: the thermally-conductive particles furthercomprise one or more of zinc oxide, boron nitride, silicon nitride,aluminum, aluminum nitride, iron, metallic oxides, graphite, and aceramic; and/or the EMI absorbing particles further comprise ferrite;and/or the thermally-conductive EMI absorber includes a cross-linker;and/or the magnetic flakes comprise: an alloy including iron, silicon,and aluminum; or an alloy including iron and nickel.
 13. A multi-pieceEMI shield comprising a frame, a removable lid or cover attachable toand removable from the frame, and the thermally-conductive EMI absorberof claim 1 along an inner surface portion of the removable lid or coverof the multi-piece EMI shield, such that the thermally-conductive EMIabsorber is compressed against a component on a printed circuit boardwhen the multi-piece EMI shield is installed to the printed circuitboard over the component.
 14. The multi-piece EMI shield of claim 13,wherein the thermally-conductive EMI absorber further comprises anadhesive layer that affixes the thermally-conductive EMI absorber to theinner surface portion of the multi-piece EMI shield.
 15. The multi-pieceEMI shield of claim 13, wherein the thermally-conductive EMI absorber isself-adhered to the inner surface portion of the multi-piece EMI shieldwithout an additional adhesive layer between the thermally-conductiveEMI absorber and the inner surface portion of the multi-piece EMIshield.
 16. The thermally-conductive EMI absorber of claim 1, wherein:the thermally-conductive EMI absorber is a gap pad having a thickness ofat least 1 millimeter or putty that is conformable even without havingto melt or undergo a phase change or reflow; and thethermally-conductive EMI absorber is configured to adjust for gaps bydeflecting at room temperature within a range from 20° C. to 25° C. 17.The thermally-conductive EMI absorber of claim 1, wherein thethermally-conductive EMI absorber is a tacky self-adherent gap pad thatis conformable even without having to melt or undergo a phase change orreflow.
 18. A thermally-conductive electromagnetic interference (EMI)absorber comprising a matrix loaded with one or more thermal conductors,one or more EMI absorbers, magnetic flakes, manganese zinc ferrite, andsilicon carbide, whereby the silicon carbide is present in apredetermined amount sufficient to generate a synergistic effect andenhance both thermal conductivity and EMI absorption of thethermally-conductive EMI absorber, and the thermally-conductive EMIabsorber is configured to have a thermal conductivity of at least 2Watts per meter per Kelvin and/or an attenuation of at least about 9decibels per centimeter for frequencies from 1 gigahertz to 6 gigahertz,and wherein the thermally-conductive EMI absorber includes about 2 to 4volume percent of the magnetic flakes, about 27 to 40 volume percent ofthe manganese zinc ferrite, and about 4 to 10 volume percent of thesilicon carbide.
 19. The thermally-conductive EMI absorber of claim 18,wherein: the one or more thermal conductors comprise alumina; and theone or more EMI absorbers comprise carbonyl iron.
 20. Thethermally-conductive EMI absorber of claim 19, wherein the matrix isloaded with the alumina, the carbonyl iron, the magnetic flakes, themanganese zinc ferrite, and the silicon carbide, such that thethermally-conductive EMI absorber includes about 2 to 4 volume percentof the magnetic flakes, about 3 to 5 volume percent of the carbonyliron, about 18 to 23 volume percent of the alumina, about 27 to 40volume percent of the manganese zinc ferrite, and about 4 to 10 volumepercent of the silicon carbide.
 21. The thermally-conductive EMIabsorber of claim 18, wherein: the thermally-conductive EMI absorber isa gap pad having a thickness of at least 1 millimeter that isconformable even without having to melt or undergo a phase change orreflow; and/or the thermally-conductive EMI absorber is configured toadjust for gaps by deflecting at room temperature within a range from20° C. to 25° C.; and/or the magnetic flakes comprise: an alloyincluding iron, silicon, and aluminum; or an alloy including iron andnickel.
 22. A thermally-conductive electromagnetic interference (EMI)absorber comprising a matrix loaded with one or morethermally-conductive particles, one or more EMI absorbing particles, andsilicon carbide, whereby the silicon carbide is present in apredetermined amount sufficient to generate a synergistic effect andenhance both thermal conductivity and EMI absorption of thethermally-conductive EMI absorber, wherein the thermally-conductive EMIabsorber includes about 4 to 10 volume percent of the silicon carbide orabout 21 to 27 volume percent of the silicon carbide.
 23. Thethermally-conductive EMI absorber of claim 22, wherein thethermally-conductive EMI absorber includes at least about 6 volumepercent of the thermally-conductive particles, at least about 8 volumepercent of the EMI absorbing particles, and at least about 21 volumepercent of the silicon carbide.
 24. The thermally-conductive EMIabsorber of claim 23, wherein the thermally-conductive EMI absorberincludes about 6 to 44 volume percent of the thermally-conductiveparticles, about 8 to 38 volume percent of the EMI absorbing particles,and about 21 to 27 volume percent of the silicon carbide.
 25. Thethermally-conductive EMI absorber of claim 22, wherein: thethermally-conductive particles comprise alumina; the EMI absorbingparticles comprise carbonyl iron; and the thermally-conductive EMIabsorber includes about 6 to 44 volume percent of the alumina, about 8to 38 volume percent of the carbonyl iron, and about 21 to 27 volumepercent of the silicon carbide.
 26. The thermally-conductive EMIabsorber of claim 22, wherein the thermally-conductive EMI absorberincludes about 32 to 49 volume percent of the EMI absorbing particles,about 18 to 23 volume percent of the thermally-conductive particles, andabout 4 to 10 volume percent of the silicon carbide.
 27. Thethermally-conductive EMI absorber of claim 22, wherein thethermally-conductive EMI absorber includes about 2 to 4 volume percentof magnetic flakes, about 3 to 5 volume percent of carbonyl iron, about18 to 23 volume percent of alumina, about 27 to 40 volume percent ofmanganese zinc ferrite, and about 4 to 10 volume percent of the siliconcarbide.
 28. A method of enhancing thermal conductivity andelectromagnetic interference (EMI) absorption of a thermally-conductiveEMI absorber, the method comprising: predetermining an amount of siliconcarbide, based on thermal conductivity and EMI absorbing properties ofthe silicon carbide, that is sufficient to synergistically enhance boththermal conductivity and EMI absorption of the thermally-conductive EMIabsorber; and adding the predetermined amount of the silicon carbide toa matrix such that the matrix is loaded with thermally-conductiveparticles, EMI absorbing particles, and the predetermined amount of thesilicon carbide to synergistically enhance both thermal conductivity andEMI absorption, wherein the thermally-conductive EMI absorber includesat least about 4 volume percent of the silicon carbide.
 29. The methodof claim 28, wherein the method includes adding the predetermined amountof silicon carbide to the matrix such that the thermally-conductive EMIabsorber includes about 4 to 10 volume percent of the silicon carbide orabout 21 to 27 volume percent of the silicon carbide.
 30. The method ofclaim 28, wherein the method includes adding the thermally-conductiveparticles, the EMI absorbing particles, and the predetermined amount ofthe silicon carbide to the matrix such that: the thermally-conductiveEMI absorber includes about 32 to 49 volume percent of the EMI absorbingparticles, about 18 to 23 volume percent of the thermally-conductiveparticles, and about 4 to 10 volume percent of the silicon carbide; orthe thermally-conductive EMI absorber includes about 6 to 44 volumepercent of the thermally-conductive particles, about 8 to 38 volumepercent of the EMI absorbing particles, and about 21 to 27 volumepercent of the silicon carbide.
 31. The method of claim 28, wherein themethod includes: adding carbonyl iron, alumina, and the predeterminedamount of the silicon carbide to the matrix such that thethermally-conductive EMI absorber includes about 6 to 44 volume percentof the alumina, about 8 to 38 volume percent of the carbonyl iron, andabout 21 to 27 volume percent of the silicon carbide; or adding magneticflakes, carbonyl iron, alumina, manganese zinc ferrite, and thepredetermined amount of the silicon carbide to the matrix such that thethermally-conductive EMI absorber includes about 2 to 4 volume percentof the magnetic flakes, about 3 to 5 volume percent of the carbonyliron, about 18 to 23 volume percent of the alumina, about 27 to 40volume percent of manganese zinc ferrite, and about 4 to 10 volumepercent of the silicon carbide.